A number carries a promise about how well it was measured.
Every measured value has digits you're sure of plus one last digit you estimated. Those are the significant figures. Zeros are the only tricky part, because some zeros are measured and some are just holding the decimal point in place.
Which digits count?
- Nonzero digits always count. 4.56 has 3.
- Captive zeros count (zeros between nonzero digits). 4.05 has 3.
- Leading zeros never count. They only place the decimal. 0.0045 has 2.
- Trailing zeros count if there's a decimal point. 4.500 has 4. So does 4500. (with a decimal point at the end).
- Trailing zeros with no decimal point are ambiguous. 4500 could be 2, 3, or 4. The convention is to count only the nonzero part, so 2. Write it in scientific notation to remove the doubt.
- Scientific notation: count only the digits in the front number. 4.50 × 10³ has 3.
Your answer can't be more precise than your worst measurement.
× and ÷
Count sig figs in each value. Round the answer to the smallest count.
2.5 × 3.42 = 8.55 → 8.6 (2 sig figs)
+ and −
Line up the decimals. Cut the answer at the column of the least precise value.
12.11 + 1.3 = 13.41 → 13.4 (one decimal place)
How many sig figs?
Round it correctly
False precision is a data-integrity problem.
A burette read to ±0.05 mL can't support a TA reported to four decimal places, and a spreadsheet that shows 0.873214% isn't more accurate than one that shows 0.87%. It just looks that way. In engineering, the sig figs in a report tell the reader what the instrument could actually resolve. Reporting more digits than that implies a calibration you don't have.
Rule of thumb for lab sheets: carry extra digits through the calculation and round once, at the end. If you round at every step, the rounding errors pile up.
Common mistakes
- Counting leading zeros in 0.00250. It has 3 sig figs, not 6.
- Using the sig-fig rule for addition. Addition uses decimal places.
- Rounding in the middle of a multi-step problem. Round only at the end.
- Applying sig figs to exact numbers. Counted items (12 eggs) and defined conversions (1 ft = 12 in, 1 kg = 1000 g) have infinite sig figs and never limit your answer.
- Writing 1200 when you mean 3 sig figs. Write 1.20 × 10³ or 1200. (with the decimal point).