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CHM 151 · Ch 3 · Stoichiometry

The Mole Map

Pick where you're starting and where you need to end up. The map walks every conversion with the units canceling as you go.

the idea

The mole is a counting unit sized so that grams and atomic masses line up.

A mole is 6.022 × 10²³ of anything. The odd number was chosen so that one carbon-12 atom weighs 12 amu and one mole of them weighs 12 grams. So the number on the periodic table means amu per atom and grams per mole at the same time. That's the bridge between the scale you can read and particles you can't count.

Plant version: moles are cases. You don't count individual cups, you count cases, and then you convert. Molar mass is the case weight, Avogadro's number is cups per case, and the coefficients in a balanced equation are the recipe ("4 cases of lactic acid per case of lactose"). Every problem in this unit is a trip through the case count.
try it

Pick a reaction, then tap a start and an end

tool

Molar mass calculator

Type any formula. Parentheses work: Ca3(PO4)2, Al(OH)3, C12H22O11.

practice

Mole map problems

engineering version

How much lactic acid can a batch make?

Fermentation turns lactose into lactic acid: C₁₂H₂₂O₁₁ + H₂O → 4 C₃H₆O₃. Milk is about 4.8% lactose. In a 1,000 kg batch, that's 48 kg of lactose, or 48,000 g ÷ 342.30 g/mol = 140 mol. At 4 mol of lactic acid per mol of lactose, it could make up to 561 mol × 90.08 g/mol ≈ 50.5 kg of lactic acid.

A finished yogurt at ~1% TA has only fermented about a fifth of that. The rest of the lactose is still there, which is why yogurt keeps acidifying in the cooler and why "post-acidification" is a shelf-life spec. Notice the mass went up from 48 kg to 50.5 kg. That isn't an error. The water in the equation adds mass.

exam traps

Common mistakes