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CHM 151 · Ch 2 · Atoms

Atomic Structure

Protons decide who you are, neutrons decide how heavy you are, and electrons decide how you behave.

the idea

Three particles, three jobs.

ParticleChargeMass (amu)WhereWhat it controls
Proton+1≈ 1nucleusIdentity. Atomic number Z. Change it and you have a different element.
Neutron0≈ 1nucleusMass and stability. Different counts give isotopes.
Electron−1≈ 0.00055around the nucleusChemistry. Bonding, charge, and reactivity. Gain or lose them and you have an ion.
Plant version: think of a lot code. The protons are the SKU, and change it and it's a different product. Neutrons are like a slight fill-weight variation, still the same SKU but heavier or lighter (isotopes). Electrons are the packaging, the outside layer that actually touches other things, which is why they drive all the reactions.

Atomic number (Z)

= protons

Mass number (A)

= protons + neutrons

Neutrons

= A − Z

Charge

= protons − electrons
try it

Build an atom

Protons
Neutrons
Electrons

The Bohr model (electrons in rings) is a simplification. It works for counting shells in elements 1–20, which is why the builder stops at calcium. Real electrons live in orbitals, covered in Electron Configuration.

isotopes

Why the periodic table says 35.45 for chlorine

No single chlorine atom weighs 35.45 amu. About 76% are Cl-35 and 24% are Cl-37. The table lists the weighted average, the same way an average fill weight works across a whole run.

Isotope mass (amu)Abundance (%)Contribution
how we got here

Four models, each fixing the last one's mistake

1803
DaltonAtoms are solid, indivisible spheres. Each element has its own kind.
1897
ThomsonDiscovered the electron. "Plum pudding": electrons stuck in a positive blob.
1911
RutherfordGold foil experiment. Most alpha particles passed straight through and a few bounced back, so the atom is mostly empty space with a tiny dense positive nucleus.
1913 → 1926
Bohr → QuantumElectrons sit in fixed energy levels. Schrödinger then replaced orbits with orbitals, regions where an electron is likely to be found.
practice

Count the particles

practice

Average atomic mass

exam traps

Common mistakes